Entropic explosion (English Wikipedia)

Analysis of information sources in references of the Wikipedia article "Entropic explosion" in English language version.

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"Archived copy". Archived from the original on 2005-02-15. Retrieved 2005-07-17.{{cite web}}: CS1 maint: archived copy as title (link)^{[full citation needed]}

Dubnikova, Faina; Kosloff, Ronnie; Yehuda, Zeiri (2006). Schubert, Hitmar; Kuznetsov, Audrey (eds.). Rational Detection Schemes for TATP NATO Advanced Research Workshop. Netherlands: Springer. pp. 111–112. ISBN 978-1402048869. Retrieved 6 February 2017."The calculated thermal decomposition pathway of the TATP molecule was a complicated multistep process with several highly reactive intermediates, including singlet molecular oxygen and various biradicals. Of note, the calculations predict the formation of acetone and ozone as the main decomposition products and not the intuitively expected oxidation products. The key conclusion from this study is that the explosion of TATP is not a thermochemically highly favored event. Rather, the explosion involves entropy burst, which is the result of the formation of 4 gas-phase molecules from every molecule of TATP in the solid state. Quite unexpectedly, the 3 isopropylidene units of the TATP molecule do not play the role of fuel that can be oxidized and release energy during the explosion. Instead, these units function as molecular scaffolds that hold the 3 peroxide units close together spatially in the appropriate orientation for the decomposition chain reaction."

Dubnikova, Faina; Kosloff, Ronnie; Almog, Joseph; Zeiri, Yehuda; Boese, Roland; Itzhaky, Harel; Alt, Aaron; Keinan, Ehud (2005). "Decomposition of Triacetone Triperoxide is an Entropic Explosion". Journal of the American Chemical Society. 127 (4): 1146–59. doi:10.1021/ja0464903. PMID 15669854.
Sinditskii, V.P; Kolesov, V.I; Egorshev, V.Yu; Patrikeev, D.I; Dorofeeva, O.V (2014). "Thermochemistry of cyclic acetone peroxides". Thermochimica Acta. 585: 10–15. doi:10.1016/j.tca.2014.03.046.
Van Duin, Adri C T; Zeiri, Yehuda; Dubnikova, Faina; Kosloff, Ronnie; Goddard, William A (2005). "Atomistic-Scale Simulations of the Initial Chemical Events in the Thermal Initiation of Triacetonetriperoxide". Journal of the American Chemical Society. 127 (31): 11053–62. doi:10.1021/ja052067y. PMID 16076213.

Dubnikova, Faina; Kosloff, Ronnie; Almog, Joseph; Zeiri, Yehuda; Boese, Roland; Itzhaky, Harel; Alt, Aaron; Keinan, Ehud (2005). "Decomposition of Triacetone Triperoxide is an Entropic Explosion". Journal of the American Chemical Society. 127 (4): 1146–59. doi:10.1021/ja0464903. PMID 15669854.
Van Duin, Adri C T; Zeiri, Yehuda; Dubnikova, Faina; Kosloff, Ronnie; Goddard, William A (2005). "Atomistic-Scale Simulations of the Initial Chemical Events in the Thermal Initiation of Triacetonetriperoxide". Journal of the American Chemical Society. 127 (31): 11053–62. doi:10.1021/ja052067y. PMID 16076213.

"In the Media | Scripps Research". Archived from the original on November 5, 2005. Retrieved July 17, 2005.

"Archived copy" (PDF). Archived from the original (PDF) on 2011-05-14. Retrieved 2005-07-17.{{cite web}}: CS1 maint: archived copy as title (link)^{[full citation needed]}

"In the Media | Scripps Research". Archived from the original on November 5, 2005. Retrieved July 17, 2005.
"Archived copy". Archived from the original on 2005-02-15. Retrieved 2005-07-17.{{cite web}}: CS1 maint: archived copy as title (link)^{[full citation needed]}
"Archived copy" (PDF). Archived from the original (PDF) on 2011-05-14. Retrieved 2005-07-17.{{cite web}}: CS1 maint: archived copy as title (link)^{[full citation needed]}