Law of mass action (English Wikipedia)

Analysis of information sources in references of the Wikipedia article "Law of mass action" in English language version.

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archive.org

  • Berthollet, C.L. (1803). Essai de statique chimique [Essay on chemical statics [i.e., equilibrium]] (in French). Paris, France: Firmin Didot. On pp. 404–407, Berthollet mentions that when he accompanied Napoleon on his expedition to Egypt, he (Berthollet) visited Lake Natron and found sodium carbonate along its shores. He realized that this was a product of the reverse of the usual reaction Na2CO3 + CaCl2 → 2NaCl + CaCO3↓ and therefore that the final state of a reaction was a state of equilibrium between two opposing processes. From p. 405: " … la décomposition du muriate de soude continue donc jusqu'à ce qu'il se soit formé assez de muriate de chaux, parce que l'acide muriatique devant se partager entre les deux bases en raison de leur action, il arrive un terme où leurs forces se balancent." ( … the decomposition of the sodium chloride thus continues until enough calcium chloride is formed, because the hydrochloric acid must be shared between the two bases in the ratio of their action [i.e., capacity to react]; it reaches an end [point] at which their forces are balanced.)

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books.google.com

  • Péter Érdi; János Tóth (1989). Mathematical Models of Chemical Reactions: Theory and Applications of Deterministic and Stochastic Models. Manchester University Press. p. 3. ISBN 978-0-7190-2208-1.
  • Guldberg, C.M.; Waage, P. (1867). Études sur les affinités chimiques [Studies of chemical affinities] (in French). Christiania [Oslo], Norway: Brøgger & Christie.

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  • Waage, P.; Guldberg, C.M. (1864). "Studier over Affiniteten" [Studies of affinities]. Forhandlinger I Videnskabs-selskabet I Christiania (Transactions of the Scientific Society in Christiania) (in Danish): 35–45.
  • Waage, P. (1864). "Forsøg til Bestemmelse af Lovene for Affiniteten" [Experiment for the determination of the laws of affinity]. Forhandlinger I Videnskabs-selskabet I Christiania (Transactions of the Scientific Society in Christiania) (in Danish): 92–94.
  • Guldberg, C.M. (1864). "Foredrag om Lovene for Affiniteten, specielt Tidens Indflydelse paa de kemiske Processer" [Lecture on the laws of affinity, especially the influence of time on chemical processes]. Forhandlinger I Videnskabs-selskabet I Christiania (Transactions of the Scientific Society in Christiania) (in Danish): 111–120.
  • van 't Hoff, J.H. (1877). "Die Grenzebene, ein Beitrag zur Kenntniss der Esterbildung" [The limit plane: a contribution to our knowledge of ester formation]. Berichte der Deutschen Chemischen Gesellschaft zu Berlin (in German). 10: 669–678. doi:10.1002/cber.187701001185.
  • Guldberg, C.M.; Waage, P. (1879). "Ueber die chemische Affinität" [On chemical affinity]. Journal für praktische Chemie. 2nd series (in German). 19: 69–114. doi:10.1002/prac.18790190111. Reprinted, with comments by Abegg in Ostwalds Klassiker der Exacten Wissenschaften, no. 104, Wilhelm Engleman, Leipzig, 1899, pp 126-171
  • (Guldberg & Waage, 1879), p. 71: "Eigentlich verstehen wir unter der activen Masse nur die Menge des Stoffes innerhalb der Actionsphäre; unter sonst gleichen Umständen kann aber die Actionsphäre durch die Volumeneinheit repräsentirt werden." (Actually we understand by "active mass" only the quantity of substance inside the sphere of action; under otherwise identical conditions, however, the sphere of action can be represented by the unit volume.)

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