Analysis of information sources in references of the Wikipedia article "Munsell color system" in English language version.
He wanted to use a decimal system making each step divisible by 5 or 10—a system which is easy to understand and easy for computer programming and cataloging. That's why Munsell used 5 principal hues—red, yellow, green, blue and purple—instead of the seven colors in the visible spectrum (ROY G BIV).