스즈키-미야우라 반응 (Korean Wikipedia)

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  • Miyaura, Norio; Yamada, Kinji; Suzuki, Akira (1979). 《A new stereospecific cross-coupling by the palladium-catalyzed reaction of 1-alkenylboranes with 1-alkenyl or 1-alkynyl halides》. 《Tetrahedron Letters》 20. 3437–3440쪽. doi:10.1016/S0040-4039(01)95429-2. hdl:2115/44006. 
  • Miyaura, Norio; Suzuki, Akira (1979). 《Stereoselective synthesis of arylated (E)-alkenes by the reaction of alk-1-enylboranes with aryl halides in the presence of palladium catalyst》. 《Chem. Comm.》. 866–867쪽. doi:10.1039/C39790000866. 
  • Miyaura, Norio; Suzuki, Akira (1995). 《Palladium-Catalyzed Cross-Coupling Reactions of Organoboron Compounds》. 《Chemical Reviews》 95. 2457–2483쪽. CiteSeerX 10.1.1.735.7660. doi:10.1021/cr00039a007. S2CID 53050782. 
  • Suzuki, Akira (1991). 《Synthetic Studies via the cross-coupling reaction of organoboron derivatives with organic halides》. 《Pure Appl. Chem.》 63. 419–422쪽. doi:10.1351/pac199163030419. 
  • Miyaura, Norio; Suzuki, Akira (1979). 《Palladium-Catalyzed Cross-Coupling Reactions of Organoboron Compounds》. 《Chemical Reviews》 95. 2457–2483쪽. CiteSeerX 10.1.1.735.7660. doi:10.1021/cr00039a007. S2CID 53050782. (Review)
  • Suzuki, Akira (1999). 《Recent advances in the cross-coupling reactions of organoboron derivatives with organic electrophiles, 1995–1998》. 《Journal of Organometallic Chemistry》 576. 147–168쪽. doi:10.1016/S0022-328X(98)01055-9. 
  • Matos, K.; Soderquist, J. A. (1998). 《Alkylboranes in the Suzuki−Miyaura Coupling: Stereochemical and Mechanistic Studies》. 《J. Org. Chem.63. 461–470쪽. doi:10.1021/jo971681s. PMID 11672034. 
  • Amatore, Christian; Jutand, Anny; Le Duc, Gaëtan (2011년 2월 18일). 《Kinetic Data for the Transmetalation/Reductive Elimination in Palladium-Catalyzed Suzuki-Miyaura Reactions: Unexpected Triple Role of Hydroxide Ions Used as Base》. 《Chemistry: A European Journal》 17. 2492–2503쪽. doi:10.1002/chem.201001911. PMID 21319240. 
  • Smith, George B.; Dezeny, George C.; Hughes, David L.; King, Anthony O.; Verhoeven, Thomas R. (1994년 12월 1일). 《Mechanistic Studies of the Suzuki Cross-Coupling Reaction》. 《The Journal of Organic Chemistry》 59. 8151–8156쪽. doi:10.1021/jo00105a036. 
  • Matos, Karl; Soderquist, John A. (1998년 2월 1일). 《Alkylboranes in the Suzuki−Miyaura Coupling: Stereochemical and Mechanistic Studies》. 《The Journal of Organic Chemistry》 63. 461–470쪽. doi:10.1021/jo971681s. PMID 11672034. 
  • Stille, John K.; Lau, Kreisler S. Y. (1977). 《Mechanisms of oxidative addition of organic halides to Group 8 transition-metal complexes》. 《Accounts of Chemical Research》 10. 434–442쪽. doi:10.1021/ar50120a002. 
  • Casado, Arturo L.; Espinet, Pablo (1998). 《On the Configuration Resulting from Oxidative Addition of RX to Pd(PPh3)4and the Mechanism of the cis-to-transIsomerization of \PdRX(PPh3)2] Complexes (R = aryl, X = halide)†》. 《Organometallics》 17. 954–959쪽. doi:10.1021/om9709502. 
  • Ridgway, Brian H.; Woerpel, K. A. (1998). 《Transmetalation of Alkylboranes to Palladium in the Suzuki Coupling Reaction Proceeds with Retention of Stereochemistry》. 《The Journal of Organic Chemistry》 63. 458–460쪽. doi:10.1021/jo970803d. PMID 11672033. 
  • Hopkinson, Matthew N.; Richter, Christian; Schedler, Michael; Glorius, Frank (June 2014). 《An overview of N-heterocyclic carbenes》 (영어). 《Nature》 510. 485–496쪽. Bibcode:2014Natur.510..485H. doi:10.1038/nature13384. ISSN 1476-4687. PMID 24965649. S2CID 672379. 
  • Casalnuovo, Albert L.; Calabrese (1990). 《Palladium-catalyzed alkylations in aqueous media》. 《J. Am. Chem. Soc.》 112. 4324–4330쪽. Bibcode:1990JAChS.112.4324C. doi:10.1021/ja00167a032. 
  • Kirchhoff, Jan H.; Netherton, Matthew R.; Hills, Ivory D.; Fu, Gregory C. (2002). 《Boronic Acids: New Coupling Partners in Room-Temperature Suzuki Reactions of Alkyl Bromides. Crystallographic Characterization of an Oxidative-Addition Adduct Generated under Remarkably Mild Conditions》. 《Journal of the American Chemical Society》 124. 13662–3쪽. Bibcode:2002JAChS.12413662K. doi:10.1021/ja0283899. PMID 12431081. 
  • Ohtaka, Atsushi (2013). 《Recyclable Polymer-Supported Nanometal Catalysts in Water》. 《The Chemical Record》 13. 274–285쪽. doi:10.1002/tcr.201300001. PMID 23568378. 
  • Martin, R.; Buchwald, S. L. (2008). 《Palladium-Catalyzed Suzuki−Miyaura Cross-Coupling Reactions Employing Dialkylbiaryl Phosphine Ligands》. 《Accounts of Chemical Research》 41. 1461–1473쪽. doi:10.1021/ar800036s. PMC 2645945. PMID 18620434. 
  • Jacks, Thomas E.; Belmont, Daniel T.; Briggs, Christopher A.; Horne, Nicole M.; Kanter, Gerald D.; Karrick, Greg L.; Krikke, James J.; McCabe, Richard J.; Mustakis; Nanninga, Thomas N. (2004년 3월 1일). 《Development of a Scalable Process for CI-1034, an Endothelin Antagonist》. 《Organic Process Research & Development》 8. 201–212쪽. doi:10.1021/op034104g. 
  • Chen, Zupeng; Vorobyeva, Evgeniya; Mitchell, Sharon; Fako, Edvin; Ortuño, Manuel A.; López, Núria; Collins, Sean M.; Midgley, Paul A.; Richard, Sylvia; Vilé, Gianvito; Pérez-Ramírez, Javier (2018). 《A heterogeneous single-atom palladium catalyst surpassing homogeneous systems for Suzuki coupling》 (PDF). 《Nature Nanotechnology》 13. 702–707쪽. Bibcode:2018NatNa..13..702C. doi:10.1038/s41565-018-0167-2. hdl:2072/359786. PMID 29941887. S2CID 49415437. 
  • Balog, Aaron; Meng, Dongfang; Kamenecka, Ted; Bertinato, Peter; Su, Dai-Shi; Sorensen, Erik J.; Danishefsky, Samuel J. (1996). 《Total Synthesis of(–)-Epothilone A》. 《Angewandte Chemie International Edition in English》 35. 2801–2803쪽. doi:10.1002/anie.199628011. 
  • Liu, Junjia; Lotesta, Stephen D.; Sorensen, Erik J. (2011). 《A concise synthesis of the molecular framework of pleuromutilin》. 《Chemical Communications》 47. 1500–2쪽. doi:10.1039/C0CC04077K. PMC 3156455. PMID 21079876. 
  • Vyvyan, J. R.; Peterson, Emily A.; Stephan, Mari L. (1999). 《An expedient total synthesis of (+/−)-caparratriene》. 《Tetrahedron Letters》 40. 4947–4949쪽. doi:10.1016/S0040-4039(99)00865-5. 
  • Han, Fu-She (2013년 1월 1일). 《Transition-metal-catalyzed Suzuki–Miyaura cross-coupling reactions: a remarkable advance from palladium to nickel catalysts》. 《Chemical Society Reviews》 42. 5270–98쪽. doi:10.1039/c3cs35521g. PMID 23460083. 
  • Percec, Virgil; Bae, Jin-Young; Hill, Dale (1995). 《Aryl Mesylates in Metal Catalyzed Homocoupling and Cross-Coupling Reactions. 2. Suzuki-Type Nickel-Catalyzed Cross-Coupling of Aryl Arenesulfonates and Aryl Mesylates with Arylboronic Acids》. 《Journal of Organic Chemistry》 60. 1060–1065쪽. doi:10.1021/jo00109a044. 
  • Inada, Kaoru; Norio Miyaura (2000). 《Synthesis of Biaryls via Cross-Coupling Reaction of Arylboronic Acids with Aryl Chlorides Catalyzed by NiCl2/Triphenylphosphine Complexes》. 《Tetrahedron》 56. 8657–8660쪽. doi:10.1016/S0040-4020(00)00814-0. 
  • Zhao, Yu-Long; Li, You; Li, Shui-Ming; Zhou, Yi-Guo; Sun, Feng-Yi; Gao, Lian-Xun; Han, Fu-She (2011년 6월 1일). 《A Highly Practical and Reliable Nickel Catalyst for Suzuki-Miyaura Coupling of Aryl Halides》. 《Advanced Synthesis & Catalysis》 353. 1543–1550쪽. doi:10.1002/adsc.201100101. 
  • Wu, Lei; Ling, Jie; Wu, Zong-Quan (2011년 6월 1일). 《A Highly Active and Recyclable Catalyst: Phosphine Dendrimer-Stabilized Nickel Nanoparticles for the Suzuki Coupling Reaction》. 《Advanced Synthesis & Catalysis》 353. 1452–1456쪽. doi:10.1002/adsc.201100134. 
  • Yang, C.T.; Zhang, Zhen-Qi; Liu, Yu-Chen; Liu, Lei (2011). 《Copper-Catalyzed Cross-Coupling Reaction of Organoboron Compounds with Primary Alkyl Halides and Pseudohalides》. 《Angew. Chem. Int. Ed.》 50. 3904–3907쪽. doi:10.1002/anie.201008007. PMID 21455914. 
  • Bredford, R.B.; Hall, Mark A.; Hodges, George R.; Huwe, Michael; Wilkinson, Mark C. (2009). 《Simple mixed Fe–Zn catalysts for the Suzuki couplings of tetraarylborates with benzyl halides and 2-halopyridines》. 《Chem. Commun.》. 6430–6432쪽. doi:10.1039/B915945B. PMID 19841799. S2CID 40428708. 
  • Nakamura, M; Hashimoto, Toru; Kathriarachchi, Kalum K. A. D. S.; Zenmyo, Takeshi; Seike, Hirofumi; Nakamura, Masaharu (2012). 《Iron-Catalyzed Alkyl-Alkyl Suzuki-Miyaura Coupling》. 《Angew. Chem. Int. Ed.》 51. 8834–883쪽. doi:10.1002/anie.201202797. PMID 22848024. 
  • Na, Y; Park, Soyoung; Han, Soo Bong; Han, Hoon; Ko, Sangwon; Chang, Sukbok (2004). 《Ruthenium-Catalyzed Heck-Type Olefination and Suzuki Coupling Reactions: Studies on the Nature of Catalytic Species》. 《J. Am. Chem. Soc.》 126. 250–258쪽. Bibcode:2004JAChS.126..250N. doi:10.1021/ja038742q. PMID 14709090. 
  • Weires, Nicholas A.; Baker, Emma L.; Garg, Neil K. (2015). 《Nickel-catalysed Suzuki–Miyaura coupling of amides》. 《Nature Chemistry》 8. 75–79쪽. Bibcode:2016NatCh...8...75W. doi:10.1038/nchem.2388. PMID 26673267. 
  • Molander, Gary A.; Biolatto, Betina (2003). 《Palladium-Catalyzed Suzuki−Miyaura Cross-Coupling Reactions of Potassium Aryl- and Heteroaryltrifluoroborates》. 《J. Org. Chem.》 68. 4302–4314쪽. doi:10.1021/jo0342368. PMID 12762730. 
  • Dolliver, Debra; Bhattarai, Bijay T.; Pandey, Arjun; Lanier, Megan L.; Bordelon, Amber S.; Adhikari, Sarju; Dinser, Jordan A.; Flowers, Patrick F.; Wills, Veronica S.; Schneider, Caroline L.; Shaughnessy, Kevin H.; Moore, Jane N.; Raders, Steven M.; Snowden, Timothy S.; McKim, Artie S.; Fronczek, Frank R. (2013). 《Stereospecific Suzuki, Sonogashira, and Negishi Coupling Reactions of N-Alkoxyimidoyl Iodides and Bromides》. 《J. Org. Chem.》 78. 3676–3687쪽. doi:10.1021/jo400179u. PMID 23534335. 
  • Asachenko, Andrey; Sorochkina, Kristina; Dzhevakov, Pavel; Topchiy, Maxim; Nechaev, Mikhail (2013). 《Suzuki–Miyaura Cross-Coupling under Solvent-Free Conditions》. 《Adv. Synth. Catal.》 355. 3553–3557쪽. doi:10.1002/adsc.201300741. 
  • Pan, Changduo; Liu, Zhang; Wu, Huayue; Din, Jinchang; Cheng, Jiang (2008). 《Palladium catalyzed ligand-free Suzuki cross-coupling reaction》. 《Catalysis Communications》 9. 321–323쪽. doi:10.1016/j.catcom.2007.06.022. 
  • Littke, Adam F.; Fu (2000). 《Versatile Catalysts for the Suzuki Cross-Coupling of Arylboronic Acids with Aryl and Vinyl Halides and Triflates under Mild Conditions》. 《J. Am. Chem. Soc.》 122. 4020–4028쪽. Bibcode:2000JAChS.122.4020L. doi:10.1021/ja0002058. 
  • Hu, Ming-Gang; Wei, Song; Jian, Ai-Ai (2007). 《Highly Efficient Pd/C-Catalyzed Suzuki Coupling Reaction ofp-(un)Substituted Phenyl Halide with (p-Substituted phenyl) Boronic Acid》. 《Chinese Journal of Chemistry》 25. 1183–1186쪽. doi:10.1002/cjoc.200790220. 
  • Saito, B; Fu (2007). 《Alkyl−Alkyl Suzuki Cross-Couplings of Unactivated Secondary Alkyl Halides at Room Temperature》. 《J. Am. Chem. Soc.》 129. 9602–9603쪽. Bibcode:2007JAChS.129.9602S. doi:10.1021/ja074008l. PMC 2569998. PMID 17628067. 
  • Kingston, J.V.; Verkade, John G. (2007). 《Synthesis and Characterization of R2PNP(iBuNCH2CH2)3N: A New Bulky Electron-Rich Phosphine for Efficient Pd-Assisted Suzuki−Miyaura Cross-Coupling Reactions》. 《J. Org. Chem.》 72. 2816–2822쪽. doi:10.1021/jo062452l. PMID 17378611. 
  • Baillie, C; Zhang, Lixin; Xiao, Jianliang (2004). 《Ferrocenyl Monophosphine Ligands: Synthesis and Applications in the Suzuki−Miyaura Coupling of Aryl Chlorides》. 《J. Org. Chem.》 69. 7779–7782쪽. doi:10.1021/jo048963u. PMID 15498017. 
  • Han, J; Liu, Y; Guo, R (2009). 《Facile synthesis of highly stable gold nanoparticles and their unexpected excellent catalytic activity for Suzuki-Miyaura cross-coupling reaction in water》. 《J. Am. Chem. Soc.》 131. 2060–2061쪽. doi:10.1021/ja808935n. PMID 19170490. 
  • Lipshutz, B.H.; Petersen, Tue B.; Abela, Alexander R. (2008). 《Room-Temperature Suzuki−Miyaura Couplings in Water Facilitated by Nonionic Amphiphiles†》. 《Org. Lett.》 10. 1333–1336쪽. doi:10.1021/ol702714y. PMID 18335944. 

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  • Matos, K.; Soderquist, J. A. (1998). 《Alkylboranes in the Suzuki−Miyaura Coupling: Stereochemical and Mechanistic Studies》. 《J. Org. Chem.63. 461–470쪽. doi:10.1021/jo971681s. PMID 11672034. 
  • Amatore, Christian; Jutand, Anny; Le Duc, Gaëtan (2011년 2월 18일). 《Kinetic Data for the Transmetalation/Reductive Elimination in Palladium-Catalyzed Suzuki-Miyaura Reactions: Unexpected Triple Role of Hydroxide Ions Used as Base》. 《Chemistry: A European Journal》 17. 2492–2503쪽. doi:10.1002/chem.201001911. PMID 21319240. 
  • Matos, Karl; Soderquist, John A. (1998년 2월 1일). 《Alkylboranes in the Suzuki−Miyaura Coupling: Stereochemical and Mechanistic Studies》. 《The Journal of Organic Chemistry》 63. 461–470쪽. doi:10.1021/jo971681s. PMID 11672034. 
  • Ridgway, Brian H.; Woerpel, K. A. (1998). 《Transmetalation of Alkylboranes to Palladium in the Suzuki Coupling Reaction Proceeds with Retention of Stereochemistry》. 《The Journal of Organic Chemistry》 63. 458–460쪽. doi:10.1021/jo970803d. PMID 11672033. 
  • Hopkinson, Matthew N.; Richter, Christian; Schedler, Michael; Glorius, Frank (June 2014). 《An overview of N-heterocyclic carbenes》 (영어). 《Nature》 510. 485–496쪽. Bibcode:2014Natur.510..485H. doi:10.1038/nature13384. ISSN 1476-4687. PMID 24965649. S2CID 672379. 
  • Kirchhoff, Jan H.; Netherton, Matthew R.; Hills, Ivory D.; Fu, Gregory C. (2002). 《Boronic Acids: New Coupling Partners in Room-Temperature Suzuki Reactions of Alkyl Bromides. Crystallographic Characterization of an Oxidative-Addition Adduct Generated under Remarkably Mild Conditions》. 《Journal of the American Chemical Society》 124. 13662–3쪽. Bibcode:2002JAChS.12413662K. doi:10.1021/ja0283899. PMID 12431081. 
  • Ohtaka, Atsushi (2013). 《Recyclable Polymer-Supported Nanometal Catalysts in Water》. 《The Chemical Record》 13. 274–285쪽. doi:10.1002/tcr.201300001. PMID 23568378. 
  • Martin, R.; Buchwald, S. L. (2008). 《Palladium-Catalyzed Suzuki−Miyaura Cross-Coupling Reactions Employing Dialkylbiaryl Phosphine Ligands》. 《Accounts of Chemical Research》 41. 1461–1473쪽. doi:10.1021/ar800036s. PMC 2645945. PMID 18620434. 
  • Chen, Zupeng; Vorobyeva, Evgeniya; Mitchell, Sharon; Fako, Edvin; Ortuño, Manuel A.; López, Núria; Collins, Sean M.; Midgley, Paul A.; Richard, Sylvia; Vilé, Gianvito; Pérez-Ramírez, Javier (2018). 《A heterogeneous single-atom palladium catalyst surpassing homogeneous systems for Suzuki coupling》 (PDF). 《Nature Nanotechnology》 13. 702–707쪽. Bibcode:2018NatNa..13..702C. doi:10.1038/s41565-018-0167-2. hdl:2072/359786. PMID 29941887. S2CID 49415437. 
  • Liu, Junjia; Lotesta, Stephen D.; Sorensen, Erik J. (2011). 《A concise synthesis of the molecular framework of pleuromutilin》. 《Chemical Communications》 47. 1500–2쪽. doi:10.1039/C0CC04077K. PMC 3156455. PMID 21079876. 
  • Han, Fu-She (2013년 1월 1일). 《Transition-metal-catalyzed Suzuki–Miyaura cross-coupling reactions: a remarkable advance from palladium to nickel catalysts》. 《Chemical Society Reviews》 42. 5270–98쪽. doi:10.1039/c3cs35521g. PMID 23460083. 
  • Yang, C.T.; Zhang, Zhen-Qi; Liu, Yu-Chen; Liu, Lei (2011). 《Copper-Catalyzed Cross-Coupling Reaction of Organoboron Compounds with Primary Alkyl Halides and Pseudohalides》. 《Angew. Chem. Int. Ed.》 50. 3904–3907쪽. doi:10.1002/anie.201008007. PMID 21455914. 
  • Bredford, R.B.; Hall, Mark A.; Hodges, George R.; Huwe, Michael; Wilkinson, Mark C. (2009). 《Simple mixed Fe–Zn catalysts for the Suzuki couplings of tetraarylborates with benzyl halides and 2-halopyridines》. 《Chem. Commun.》. 6430–6432쪽. doi:10.1039/B915945B. PMID 19841799. S2CID 40428708. 
  • Nakamura, M; Hashimoto, Toru; Kathriarachchi, Kalum K. A. D. S.; Zenmyo, Takeshi; Seike, Hirofumi; Nakamura, Masaharu (2012). 《Iron-Catalyzed Alkyl-Alkyl Suzuki-Miyaura Coupling》. 《Angew. Chem. Int. Ed.》 51. 8834–883쪽. doi:10.1002/anie.201202797. PMID 22848024. 
  • Na, Y; Park, Soyoung; Han, Soo Bong; Han, Hoon; Ko, Sangwon; Chang, Sukbok (2004). 《Ruthenium-Catalyzed Heck-Type Olefination and Suzuki Coupling Reactions: Studies on the Nature of Catalytic Species》. 《J. Am. Chem. Soc.》 126. 250–258쪽. Bibcode:2004JAChS.126..250N. doi:10.1021/ja038742q. PMID 14709090. 
  • Weires, Nicholas A.; Baker, Emma L.; Garg, Neil K. (2015). 《Nickel-catalysed Suzuki–Miyaura coupling of amides》. 《Nature Chemistry》 8. 75–79쪽. Bibcode:2016NatCh...8...75W. doi:10.1038/nchem.2388. PMID 26673267. 
  • Molander, Gary A.; Biolatto, Betina (2003). 《Palladium-Catalyzed Suzuki−Miyaura Cross-Coupling Reactions of Potassium Aryl- and Heteroaryltrifluoroborates》. 《J. Org. Chem.》 68. 4302–4314쪽. doi:10.1021/jo0342368. PMID 12762730. 
  • Dolliver, Debra; Bhattarai, Bijay T.; Pandey, Arjun; Lanier, Megan L.; Bordelon, Amber S.; Adhikari, Sarju; Dinser, Jordan A.; Flowers, Patrick F.; Wills, Veronica S.; Schneider, Caroline L.; Shaughnessy, Kevin H.; Moore, Jane N.; Raders, Steven M.; Snowden, Timothy S.; McKim, Artie S.; Fronczek, Frank R. (2013). 《Stereospecific Suzuki, Sonogashira, and Negishi Coupling Reactions of N-Alkoxyimidoyl Iodides and Bromides》. 《J. Org. Chem.》 78. 3676–3687쪽. doi:10.1021/jo400179u. PMID 23534335. 
  • Saito, B; Fu (2007). 《Alkyl−Alkyl Suzuki Cross-Couplings of Unactivated Secondary Alkyl Halides at Room Temperature》. 《J. Am. Chem. Soc.》 129. 9602–9603쪽. Bibcode:2007JAChS.129.9602S. doi:10.1021/ja074008l. PMC 2569998. PMID 17628067. 
  • Kingston, J.V.; Verkade, John G. (2007). 《Synthesis and Characterization of R2PNP(iBuNCH2CH2)3N: A New Bulky Electron-Rich Phosphine for Efficient Pd-Assisted Suzuki−Miyaura Cross-Coupling Reactions》. 《J. Org. Chem.》 72. 2816–2822쪽. doi:10.1021/jo062452l. PMID 17378611. 
  • Baillie, C; Zhang, Lixin; Xiao, Jianliang (2004). 《Ferrocenyl Monophosphine Ligands: Synthesis and Applications in the Suzuki−Miyaura Coupling of Aryl Chlorides》. 《J. Org. Chem.》 69. 7779–7782쪽. doi:10.1021/jo048963u. PMID 15498017. 
  • Han, J; Liu, Y; Guo, R (2009). 《Facile synthesis of highly stable gold nanoparticles and their unexpected excellent catalytic activity for Suzuki-Miyaura cross-coupling reaction in water》. 《J. Am. Chem. Soc.》 131. 2060–2061쪽. doi:10.1021/ja808935n. PMID 19170490. 
  • Lipshutz, B.H.; Petersen, Tue B.; Abela, Alexander R. (2008). 《Room-Temperature Suzuki−Miyaura Couplings in Water Facilitated by Nonionic Amphiphiles†》. 《Org. Lett.》 10. 1333–1336쪽. doi:10.1021/ol702714y. PMID 18335944. 

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