See (Harary & Sumner 1980). Harary, Frank; Sumner, David (1980), "The dichromatic number of an oriented tree", Journal of Combinatorics, Information & System Sciences, 5 (3): 184–187, MR0603363.
Cayley (1857) "On the theory of the analytical forms called trees,"Philosophical Magazine, 4th series, 13 : 172–176. However it should be mentioned that in 1847, K.G.C. von Staudt, in his book Geometrie der Lage (Nürnberg, (Germany): Bauer und Raspe, 1847), presented a proof of Euler's polyhedron theorem which relies on trees on pages 20–21. Also in 1847, the German physicist குசுத்தாவ் கிர்க்காஃப் investigated electrical circuits and found a relation between the number (n) of wires/resistors (branches), the number (m) of junctions (vertices), and the number (μ) of loops (faces) in the circuit. He proved the relation via an argument relying on trees. See: Kirchhoff, G. R. (1847) "Ueber die Auflösung der Gleichungen, auf welche man bei der Untersuchung der linearen Vertheilung galvanischer Ströme geführt wird" (On the solution of equations to which one is led by the investigation of the linear distribution of galvanic currents), Annalen der Physik und Chemie, 72 (12) : 497–508.