五氟合氙酸四甲基铵 (Chinese Wikipedia)

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The pentafluoroxenate(IV) anion, XeF₅⁻: the first example of a pentagonal planar AX5 species, Christe K. O., Curtis E. C., Dixon D. A., Mercier H. P.,. Sanders J. C. P, Schrobilgen G. J.,J. Am. Chem. Soc.; 1991; 113(9); 3351-3361 doi:10.1021/ja00009a021